Stereochemistry of Organic Compounds

Stereochemistry of Organic Compounds: A Detailed Look -- Section 8 of Organic Chemistry Notes is 16 pages in length (page 8-1 through page 8-16) and covers ALL you'll need to know about the following lecture/book topics:

SECTION 8 – Stereochemistry: A Detailed Look

8-1 -- Definitions
_· Chiral, Achiral, Enantiomers, and Stereogenic Centers
_· Interior Mirror Planes
8-2 -- Enantiomers
_· Interactions of Enantiomers with Other Reactants (ex. Acylose)
_· Rotation of Plane-Polarized Light
_· Angle of Rotation
_· Dextrorotatory (D) or (+) vs. Levorotatory (L) or (-)
_· Absolute Configurations “R” and “S”
_· Racemic Mixtures and Racemates
8-4 -- Specifying Absolute Configurations
_· How to Determine “R” and “S” Enantiomers
_· Cyclic Permutations
8-5 -- Compounds with Multiple Stereocenters
_· Diastereomers
_· Meso Compounds and Planes of Symmetry
8-6 -- Cyclic Compounds
8-7 -- Isomer Types – A Summary
8-8 -- Fischer Projections
8-9 -- Manipulating Fischer Projections

_· Allowed Operations
_· 180° Rotation (Allowed)
_· Cyclic Permutations of 3 Substituents (Allowed)
_· Forbidden Operations
_· Swapping only 2 Substituents (Forbidden)
_· 90° Rotation in the Plane (Forbidden)
8-10 -- Organic Reactions – Stereochemical Considerations
_· Achiral Reactants
_· Diastereomers
_· Optically Active (Chiral) Reactants
8-15 -- Conformational Enantiomers
_· Chair Conformations and Enantiomeric Cyclohexanes
_· Racemates of Substituted Cyclohexane Products

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Stereochemistry of Organic Compounds

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